Open terminal (Alt+Shift+T) and paste the following line:
sudo update-alternatives --config x-www-browser
Then it should prompts for your input:
There are 2 choices for the alternative x-www-browser (providing /usr/bin/x-www-browser). Selection Path Priority Status ------------------------------------------------------------ 0 /usr/bin/google-chrome-stable 200 auto mode 1 /usr/bin/firefox 40 manual mode * 2 /usr/bin/google-chrome-stable 200 manual mode Press enter to keep the current choice[*], or type selection number:
I want to keep it as firefox, so I would enter 1 in my case. The next it starts up, firefox would be my default browser instead of chrome 🙂
Source: http://ubuntuforums.org/showthread.php?t=1607996